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71.
A procedure for the determination of trace level of copper(II) and cadmium(II) by FAAS using an on-line preconcentration system has been proposed. In this system, copper and cadmium ions were adsorbed onto a minicolumn packed with silica gel modified with niobium(V) oxide (Nb2O5-SiO2), followed by nitric acid elution in reverse mode and determination on-line by flame atomic absorption spectrometry (AAS) without interference of the matrix. Chemical and flow variables as well as concomitant ions were studied in the developed procedure. The enrichment factor for copper(II) and cadmium(II) was 34.2 and 33.0, respectively, using a preconcentration time of 2 min. The limit of detection for copper(II) and cadmium(II) was 0.4, and 0.1 μg l−1, respectively. The precision of the method, evaluated as the relative standard deviation in solutions containing 15 μg l−1 of copper and 10 μg l−1 of cadmium, by analyzing a series of seven replicates, was 1.8 and 1.6%, respectively. The accuracy was assessed through recovery experiments of certified material and water samples. 相似文献
72.
73.
Joseane Sarmento Lazarotto Vitória de Lima Brombilla Siara Silvestri Edson Luiz Foletto 《应用有机金属化学》2020,34(12):e6001
A novel composite, biochar derived from spent coffee grounds with immobilized TiO2 (biochar–TiO2) was prepared, characterized, and applied as an alternative, effective, and sustainable photocatalyst for degrading diclofenac from aqueous solution. Composites with different mass ratios between TiO2 and biochar were prepared by mechanical mixing and subsequent pyrolysis in an inert atmosphere of N2 at 650°C. The sample with biochar–TiO2 ratio of 1:1 presented a degradation efficiency of 90% at just 120 min versus 40% for TiO2 used as reference. This fact is associated with a set of intrinsic characteristics obtained during the formation of the composite, such as superior pore size, avoiding the recombination of the ē/h+ pair, bandgap reduction, and promotion of reactive oxygen species due to phenolic groups present on the biochar surface. The dominant reactive species involved during the photocatalytic degradation of diclofenac were h+ and •OH. The diclofenac degradation pathways were determined based on the identification of intermediates and nonpurgeable organic carbon (NPOC) analysis. The novel biochar–TiO2 composite prepared in this work showed high physical–chemical stability and efficiency over five consecutive cycles of reuse, proving to be a highly promising photocatalyst for degrading diclofenac in water. 相似文献
74.
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76.
Amal Al-Kahlout Diogo Vieira César O. Avellaneda Edson R. Leite Michel A. Aegerter Agnieszka Pawlicka 《Ionics》2010,16(1):13-19
Proton-conducting gel polymer electrolytes based on gelatin plasticized with glycerol and containing acetic acid were investigated,
characterized, and applied to electrochromic window. For glycerol contents varying from 7% to 48%, the conductivity of the
uniform and predominantly amorphous gel electrolyte was found to follow a Vogel–Tamman–Fulcher behavior with the temperature.
Typically, for the electrolyte chosen to make 7 × 2 cm2 electrochromic smart window with the configuration: glass/fluor-doped tin oxide (FTO)/WO3/gelatin electrolyte/CeO2–TiO2/FTO/glass and containing 28% of glycerol, the conductivities were found to be of the order of 5 × 10−5 S/cm at room temperature and 3.6 × 10−4 S/cm at 80 °C. The device was characterized by spectroelectrochemical techniques and was tested up to 10,000 cycles showing
a fast coloring/bleaching behavior, where the coloring process was achieved in 10 s and the bleaching in 2 s. The transmission
variation at the wavelength of 550 nm was about 15%. The cyclic voltammograms showed a very good reversibility of the cathodic/anodic
processes, and the charge density was about 3.5 mC/cm2. The memory tests showed that the transmittance in the colored state increased by 8% in 90 min after removing the potential. 相似文献
77.
Synthesis of niobia nanocrystals with controlled morphology 总被引:1,自引:0,他引:1
In this work, TT niobia-phase nanocrystals with controlled morphology were obtained by the hydrothermal treatment of a niobium peroxo complex precursor at very low temperatures. The materials obtained by this route presented a very high surface area (ranging from 79 to 327 m(2)/g), disordered NbO(6), NbO(7), and NbO(8) polyhedra, Nb-O superficial sites, and a superficial OH group, which must have ensured the acidic characteristics of this oxide. 相似文献
78.
Roney L. Thompson Edson J. Soares Raphael D.A. Bacchi 《ournal of non Newtonian Fluid Mechanics》2010,165(7-8):448-452
In this note, we present some results concerning the gas displacement of power-law liquids and visco-plastic Papanastasiou’s materials improving the understanding of the problem considered in Sousa et al. (2007) [1]. Specifically, we present: the fraction of mass attached to the wall for a viscosity-thickening power-law fluid, different transition patterns between by pass and full-recirculating flow regimes, expressions for the critical (in the sense proposed by Soares and Thompson (2009) [2]) fraction of residual mass as a function of the rheological parameter of interest, and fields of yielded and unyielded zones for the visco-plastic material. 相似文献
79.
Iêda Maria Garcia dos Santos Rafael Carlos Martins Moreira Ronan Lebullenger Edson Roberto Leite Elson Longo 《Journal of Non》2003,319(3):304-310
PbO-Bi2O3-Ga2O3 glasses present interesting properties such as good transmission in the mid-infrared region, high magnetic Verdet constant and non-linear properties. The processing of these heavy-metal-oxide (HMO) glasses is limited by the high corrosive nature of the melt, even in relation to noble metal crucibles. In this work, three kinds of ceramic crucibles (alumina, tin oxide and zirconia) were tested for melting HMO glasses. The main physical properties of the prepared glasses, such as the characteristic temperatures, optical transmission were studied in function of the crucible nature, time/temperature melting parameters. The incorporation of crucible material in the glasses was determined by ICP and atomic absorption. The maximum glass contamination from the crucible was 2.9, 1.6 and 3.6 mol% for Al2O3, SnO2 and ZrO2 crucibles, respectively, when melting was done at 900 °C/240 min, for zirconia crucibles and at 1000 °C/60 min, for the other two crucibles. The evolution of the physical properties was discussed as a function of contamination degree. 相似文献
80.
Edson de Faria 《Proceedings of the American Mathematical Society》1998,126(1):67-74
Using general bounds on the conformal distortion of univalent maps, we prove a strong version of Sullivan's sector theorem, which gives certain sufficient conditions for an arbitrarily long composition of univalent Herglotz functions to map the upper half-plane into a proper sub-sector.